Adsorption of 1-(1-naphthyl)ethylamine from solution onto platinum surfaces: implications for the chiral modification of heterogeneous catalysts.
Adsorption of 1-(1-naphthyl)ethylamine from solution onto platinum surfaces: implications for the chiral modification of heterogeneous catalysts.
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1-(1-萘基)乙胺从溶液中吸附到铂表面上：对多相催化剂手性改性的影响。
DOI：
10.1002/anie.201209815
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发表时间：
2013
影响因子：
--
通讯作者：
F. Zaera
中科院分区：
文献类型：
--
作者：
Alexander D. Gordon;F. Zaera
催化剂的手性改性：对溶液中1-（1-萘基）乙胺在Pt表面上的吸附进行的原位反射-吸收红外光谱比较研究表明，键合主要通过胺基而不是通常认为的芳环进行（见图）。鉴于这些结果，可能需要重新思考现有的催化剂手性修饰模型。
Chiral modification of catalysts: A comparative in situ reflection–absorption infrared spectroscopy study of the adsorption of 1‐(1‐naphthyl) ethylamine on Pt surfaces from solution indicated bonding mainly through the amine group and not the aromatic ring as commonly assumed (see picture). In light of these results, a rethinking of the existing model for chiral modification of catalysts may be needed.