Super Uranophiles: Application to Highly Effective Solvent Extraction of Uranyl Ion in the Presence of Methyltrioctylammonium Chloride

Super Uranophiles: Application to Highly Effective Solvent Extraction of Uranyl Ion in the Presence of Methyltrioctylammonium Chloride
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超级亲铀剂:在甲基三辛基氯化铵存在下高效溶剂萃取铀酰离子的应用

DOI:
10.1246/cl.1999.1275
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发表时间:
1999
期刊:
影响因子:
--
通讯作者:
I. Yoshida
I. Yoshida
中科院分区:
--
文献类型:
--
作者:
M. Nishida;M. Sonoda;D. Ishii;I. Yoshida

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在甲基三辛基氯化铵存在下,以氯仿为萃取剂,羟基杯[n]芳烃对磺酸盐Hj1nn−(n=6和8)作为超亲铀试剂,有效地萃取了水溶液中的铀酰离子UO22+。所提取的离子缔合物为[(UO22+)(168−)(H+)−3](MTA+)9和[(UO22+)2(1812−)(H+)−3](MTA+)11。
By using hydroxycalix[n]arene-p-sulfonates, Hj1nn− (n = 6 and 8) known as super uranophiles, uranyl ion, UO22+, in aqueous solution was efficiently extracted by chloroform in the presence of methyltrioctylammonium chloride, MTA+Cl−. The extracted species were found to be the ionic associates, [(UO22+)(168−)(H+)−3](MTA+)9 and [(UO22+)2(1812−)(H+)−3](MTA+)11.
DOI: 10.1021/ja00269a045
发表时间: 1986-04-30
影响因子: 15
作者:
SHINKAI, S;MORI, S;MANABE, O
通讯作者: MANABE, O