Studying Fast Reaction Kinetics with Online NMR Spectroscopy
Studying Fast Reaction Kinetics with Online NMR Spectroscopy
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DOI：
10.1002/cite.201600068
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发表时间：
2017-04
影响因子：
1.9
通讯作者：
E. Harbou;R. Behrens;Jürgen Berje;A. Brächer;H. Hasse
中科院分区：
文献类型：
--
作者：
E. Harbou;R. Behrens;Jürgen Berje;A. Brächer;H. Hasse
本文介绍了一种液体恒温微反应器核磁共振探针头，用于快反应动力学的研究。通过这种设置，可以在宽的温度（~ 20 - 100 °C）和压力范围（0 - 60巴）内研究反应动力学。的设置和NMR探头讨论从反应工程的角度来看，基于实验和模拟。微反应器探头大大拓宽了在线NMR光谱在反应和过程监测中的应用范围。
A liquid thermostated microreactor Nuclear Magnetic Resonance (NMR) probe head is presented that facilitates the investigation of kinetics of fast reactions. With this setup, reaction kinetics can be studied in a broad temperature (–20 – 100 °C) and pressure range (0 – 60 bar). The setup and NMR probe head are discussed from a reaction engineering standpoint based on experiments and simulations. The microreactor probe head widens significantly the range of applications of online NMR spectroscopy for reaction and process monitoring.