Self-assembled metal-organic polyhedra: An overview of various applications
Self-assembled metal-organic polyhedra: An overview of various applications
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DOI：
10.1016/j.ccr.2015.05.016
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发表时间：
2016
影响因子：
20.6
通讯作者：
H. Vardhan;M. Yusubov;F. Verpoort
中科院分区：
文献类型：
--
作者：
H. Vardhan;M. Yusubov;F. Verpoort
自组装是一种有效的合成工具，它允许化学家从相对简单的起始材料设计出许多复杂的结构，各种形状的超分子。金属有机多面体是自组装超分子家族中新兴且有前途的成员，具有直接源自前体单元的迷人结构和功能。在过去的二十年中，在这一领域的研究取得了迅速的进展，现在的目标是实现各种应用，如生物医学，催化，分子传感，气体吸附和分离，以及从多面体合成金属有机框架。这次审查将集中在每一个应用程序与各种前所未有的例子，并强调一些挑战仍然需要解决。
Self-assembly is a potent synthetic tool that allowed chemists to design numerous complex structures, supramolecules of various shapes from relatively simple starting materials. Metal–organic polyhedra are a rising and promising member of the self-assembled supramolecule family possessing fascinating structures and functionalities directly deriving from the precursor units. During the last two decades, research in this field has been briskly progressed and it is now objective to exemplify various applications such as biomedical, catalysis, molecular sensing, gas adsorption and separation, and synthesis of metal–organic frameworks from polyhedra. This review will be focus on each and every application with various unprecedented examples and highlight few challenges still need to be address.