Fluctuations in energy in completely open small systems
Fluctuations in energy in completely open small systems
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DOI：
10.1021/nl020295
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发表时间：
2002-06-01
期刊：
影响因子：
10.8
通讯作者：
Chamberlin, RV
中科院分区：
文献类型：
--
作者：
Hill, TL;Chamberlin, RV
导出了小的完全开放的Mu、p、T和Mu、T或Mu(1)、Mu(2)、T(不可压缩)系统中能量涨落的一般方程。本文考虑了四个例子。正如预期的那样，波动异常大，因为对系统的规模没有限制。此外，N和V或N-1和N-2的波动也间接导致了E的波动。
General equations are derived for fluctuations in energy in small completely open mu, p, T and mu, T or mu(1), mu(2), T (incompressible) systems. Four examples are considered. As expected, the fluctuations are unusually large because there are no restraints on the size of the system. Also, fluctuations in N and V or in N-1 and N-2 contribute indirectly to the fluctuations in E.