Processing and characterization of amorphous polyethylene terephthalate fibers for the alignment of carbon nanofillers in thermosetting resins
Processing and characterization of amorphous polyethylene terephthalate fibers for the alignment of carbon nanofillers in thermosetting resins
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DOI：
10.1002/pc.23366
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发表时间：
2015-06-01
影响因子：
5.2
通讯作者：
Maffezzoli, Alfonso
中科院分区：
文献类型：
--
作者：
Greco, Antonio;Lionetto, Francesca;Maffezzoli, Alfonso
The engineering aspects, which are associated with the development of nanocomposites, involve in either final properties or processability of nanocomposites. Both are affected by the distribution of nanofiller in the matrix and by the aspect ratio of the nanofiller. A nanofilled thermosetting resin can be exploited as a matrix for continuous fibers when the alignment of a high aspect ratio nanofiller is achieved, and in this case, a hierarchical composite is obtained. In this study, a new procedure for the alignment of nanofillers in a thermosetting matrix is proposed. The two-step approach is based on (i) the alignment of nanofillers (carbon nanotubes, graphene, etc.) in thermoplastic fibers by a fiber spinning process and (ii) the use of these nanocomposite fibers as a carrier to bring aligned nanofillers into a reactive thermosetting resin. These fibers, soluble in the thermosetting resin, release the nanofillers orientated according to the direction in which fibers are positioned, even after the curing of the matrix. The proof of concept is demonstrated by producing melt spun polyethylene terephtalate (PETg) fibers filled with graphene nanoplatelets (GNP) and multiwall carbon nanotubes (MWCNT) with a very high filler content (up to 10 wt%) in view of producing a hierarchical composite. POLYM. COMPOS., 36:1096-1103, 2015. (c) 2015 Society of Plastics Engineers
