Reversible-deactivation radical polymerization mediated by CuSO4·5H2O: an alternative and promising copper(II)-based catalyst
Reversible-deactivation radical polymerization mediated by CuSO4·5H2O: an alternative and promising copper(II)-based catalyst
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DOI：
10.1039/c2py20639k
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发表时间：
2012-10
影响因子：
4.6
通讯作者：
Junfei Zhao;Wen-Xia Wang;L. Bai;Lili Zhou;Zhenping Cheng;Zhengbiao Zhang;Xiu-lin Zhu
中科院分区：
文献类型：
--
作者：
Junfei Zhao;Wen-Xia Wang;L. Bai;Lili Zhou;Zhenping Cheng;Zhengbiao Zhang;Xiu-lin Zhu
This work demonstrated a successful example of RDRP with CuSO4·5H2O as a Cu(II) based catalyst in the presence of a reducing agent. CuSO4·5H2O produced a more controllable polymerization compared with the widely used CuBr2. The mechanism was revealed to be a Cu(0)-mediated RDRP with the in situ generated Cu(0) from CuSO4·5H2O as the catalyst. This work may provide an alternative, economical and promising copper(II)-based RDRP catalyst, which would eventually enrich and benefit the RDRP technique.
