Synthesis and spectroscopic and electrical properties of [W(C3S5)3]2- and [Mo(C3S5)3]2- anion complexes and their oxidized species and x-ray crystal structures of [NBun4]2[W(C3S5)3], [NBun4]2[Mo(C3S5)3], and [Fe(C5Me5)2][W(C3S5)3]
Synthesis and spectroscopic and electrical properties of [W(C3S5)3]2- and [Mo(C3S5)3]2- anion complexes and their oxidized species and x-ray crystal structures of [NBun4]2[W(C3S5)3], [NBun4]2[Mo(C3S5)3], and [Fe(C5Me5)2][W(C3S5)3]
复制标题
[W(C3S5)3]2- 和 [Mo(C3S5)3]2- 阴离子配合物及其氧化物质的合成、光谱和电学性质以及 [NBun4]2[W(C3S5)3] 的 X 射线晶体结构
DOI：
10.1021/ic00078a015
复制
发表时间：
1993
期刊：
影响因子：
--
通讯作者：
W. Mori
中科院分区：
文献类型：
--
作者：
G. Matsubayashi;K. Douki;H. Tamura;M. Nakano;W. Mori
制备[NBu n 4 ] 4 °W(C 3 S 5 ) 3 ]和[NBu n 4 ] 2 °Mo(C 3 S 5 ) 3 ][C 3 S 5 2- =4,5-二巯基-1,3-二硫醇-2-硫代酸酯(2-)]。单晶 X 射线结构分析揭示了两个阴离子部分在金属原子周围存在扭曲的三角棱柱配位。它们被[Fe(C 5 Me 5 ) 2 ][BF 4 ]氧化，分别得到[Fe(C 5 Me 5 ] 2 [W(C 3 S 5 ) 3 ]和[Fe(C 5 Me 5 ) 2 ][Mo(C 3 S 5 ) 3 ]
[NBu n 4 ] 4 °W(C 3 S 5 ) 3 ] and [NBu n 4 ] 2 °Mo(C 3 S 5 ) 3 ] [C 3 S 5 2- =4,5-dimercapto-1,3-dithiole-2-thionate(2-)] were prepared. Single-crystal X-ray structure analyses revealed a distorted trigonal prismatic coordination around the metal atom for both the anion moieties. They were oxidized by [Fe(C 5 Me 5 ) 2 ][BF 4 ] to afford [Fe(C 5 Me 5 ] 2 [W(C 3 S 5 ) 3 ] and [Fe(C 5 Me 5 ) 2 ][Mo(C 3 S 5 ) 3 ], respectively