Enantioselective Synthesis of Allylic Esters via Asymmetric Allylic Substitution with Metal Carboxylates Using Planar-Chiral Cyclopentadienyl Ruthenium Catalysts
Enantioselective Synthesis of Allylic Esters via Asymmetric Allylic Substitution with Metal Carboxylates Using Planar-Chiral Cyclopentadienyl Ruthenium Catalysts
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DOI：
10.1021/ja908456b
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发表时间：
2010-02-03
影响因子：
15
通讯作者：
Onitsuka, Kiyotaka
中科院分区：
文献类型：
--
作者：
Kanbayashi, Naoya;Onitsuka, Kiyotaka
已经开发出使用平面手性环戊二烯基钌配合物用羧酸钠进行不对称烯丙基取代。以良好的产率制备了具有高区域和对映选择性的光学活性烯丙酯。
An asymmetric allylic substitution with sodium carboxylate using a planar-chiral cyclopentadienyl ruthenium complex has been developed. Optically active allylic esters were prepared in good yields with high regio- and enantioselectivities.