Cyclopentadienyl titanium chlorides containing ortho-(1-naphthyl)phenoxide ligation
Cyclopentadienyl titanium chlorides containing ortho-(1-naphthyl)phenoxide ligation
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含有邻-(1-萘基)苯氧基连接的环戊二烯基氯化钛
DOI：
10.1039/a805034a
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发表时间：
1998
影响因子：
4.9
通讯作者：
I. Rothwell
中科院分区：
文献类型：
--
作者：
Jonathan S. Vilardo;M. Thorn;P. Fanwick;I. Rothwell
研究了一系列含邻(1-萘基)苯氧基配体的钛单环戊二烯衍生物； d1–d1 物质 [Cp(ArO)Ti(μ-Cl)2Ti(OAr)Cp] 中的 Ti-Ti 距离恰好介于顺磁性 [Cp2Ti(μ-Cl)2TiCp2] 和抗磁性 [(ArO)2Ti(μ-Cl)2Ti(OAr)2] 之间。
A series of mono-cyclopentadiene derivatives of titanium containing ortho-(1-naphthyl)phenoxide ligands have been studied; the Ti–Ti distance in the d1–d1 species [Cp(ArO)Ti(µ-Cl)2Ti(OAr)Cp] is exactly intermediate between that found in paramagnetic [Cp2Ti(µ-Cl)2TiCp2] and diamagnetic [(ArO)2Ti(µ-Cl)2Ti(OAr)2].