THERMODYNAMIC TABLES FOR NUCLEAR WASTE ISOLATION, V.1: AQUEOUS SOLUTIONS DATABASE
THERMODYNAMIC TABLES FOR NUCLEAR WASTE ISOLATION, V.1: AQUEOUS SOLUTIONS DATABASE
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核废料隔离热力学表，V.1：水溶液数据库
DOI：
10.2172/929657
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发表时间：
1988
期刊：
影响因子：
--
通讯作者：
L. Silvester
中科院分区：
文献类型：
--
作者：
S. Phillips;F. Hale;L. Silvester
给出了核废料分离的一致性热力学性质值表。表中包括生成吉布斯能的严格评估值。矿物的生成焓、熵和热容;固体;水离子;在25 ℃和零离子强度下选定的锕系元素和裂变衰变产物的离子对和复合离子。这些固有的数据被用来计算平衡常数和标准电位与典型的实验测量和其他工作进行了比较。对进一步的研究提出了建议。
Tables of consistent thermodynamic property values for nuclear waste isolation are given. The tables include critically assessed values for Gibbs energy of formation. enthalpy of formation, entropy and heat capacity for minerals; solids; aqueous ions; ion pairs and complex ions of selected actinide and fission decay products at 25{sup o}C and zero ionic strength. These intrinsic data are used to calculate equilibrium constants and standard potentials which are compared with typical experimental measurements and other work. Recommendations for additional research are given.