Highly Selective and Near-Quantitative Conversion of Fructose to 5-Hydroxymethylfurfural Using Mildly Acidic Ionic Liquids
Highly Selective and Near-Quantitative Conversion of Fructose to 5-Hydroxymethylfurfural Using Mildly Acidic Ionic Liquids
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DOI：
10.1021/sc400553q
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发表时间：
2014-04-01
影响因子：
8.4
通讯作者：
Hallett, Jason P.
中科院分区：
文献类型：
--
作者：
Eminov, Sanan;Wilton-Ely, James D. E. T.;Hallett, Jason P.
室温离子液体[C（4）C（1）im][HSO 4]提供了一种多方面的介质，可将果糖转化为多功能化学结构单元5-羟甲基糠醛（HMF）。为了确定优化该工艺所需的一些特性，已经研究了一系列金属盐。这导致了果糖在系统中几乎定量地转化为5-HMF，该系统对所需产物具有选择性，能量密集度更低，并且比商业方法更环保。
The room-temperature ionic liquid, [C(4)C(1)im][HSO4], provides a multi-faceted medium in which to convert fructose to the versatile chemical building block, 5-hydroxymethylfurfural (HMF). A range of metal salts have been investigated in order to establish some of the properties required for the optimization of this process. This has led to almost quantitative conversion of fructose to 5-HMF in a system that is both selective for the desired product, less energy intensive, and more environmentally benign than the commercial process.