Synthesis, Reactions, and Selected Physico-Chemical Properties of 1,3- and 1,2-tetrachalcogenafulvalenes
Synthesis, Reactions, and Selected Physico-Chemical Properties of 1,3- and 1,2-tetrachalcogenafulvalenes
复制标题
1,3- 和 1,2- 四硫属富瓦烯的合成、反应和选定的物理化学性质
DOI：
10.1002/chin.198826342
复制
发表时间：
1988
期刊：
影响因子：
--
通讯作者：
Fanghaenel Egon
中科院分区：
文献类型：
--
作者：
G. Schukat;A. M. Richter;Fanghaenel Egon
本文综述了1，3-和1，2-四硫代富瓦烯的合成、取代基的化学转化、环系反应以及主链和侧链上含有1，3-四硫富瓦烯单元的聚合物的合成。对于所选择的四硫代富瓦烯电荷转移络合物，分别讨论了分子结构和固态结构与电导率的关系。报道了几种以四硫富瓦烯为给体的电荷转移络合物的超导性质。本文综述了合成四硫杂富瓦烯的重要起始化合物(如1，2-和1，3-二硫醇、1，3-硫杂硒和1，3-二硒醇衍生物)的制备方法。1，2-和1，3-四硫基富瓦烯的选定性质(熔点、UV-Vis吸收数据和氧化电位)汇总在适当的表格中。
Abstract This review describes the synthesis of 1,3- and 1,2-tetrachalcogenafulvalenes, the chemical transformation of substituents, reactions of the ring system, and the synthesis of polymers with 1,3-tetrathiafulvalene units in the backbone and in the side chain. For selected charge-transfer complexes of tetrachalcogenafulvalenes, the relation between molecular structure and solid-state structure, respectively, and electric conductivity are discussed. Superconducting properties of some charge-transfer complexes with tetrachalcogenafulvalenes as donor are reported. Preparations of important starting compounds for the synthesis of tetrachalcogenafulvalenes (such as 1,2- and 1,3-dithiole, 1,3-thiaselenole, and 1,3-diselenole derivatives) have been considered in this review. Selected properties (melting point, UV‐Vis absorption data and oxidation potentials) of 1,2- and 1,3-tetrachalcogenafulvalenes are summarized in appropriate tables.
影响因子：
2.8
作者：
G. Habermehl
通讯作者：
G. Habermehl