Scalable, Metal- and Additive-Free, Photoinduced Borylation of Haloarenes and Quaternary Arylammonium Salts.
Scalable, Metal- and Additive-Free, Photoinduced Borylation of Haloarenes and Quaternary Arylammonium Salts.
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DOI：
10.1021/jacs.6b01376
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发表时间：
2016-03-09
影响因子：
15
通讯作者：
Larionov OV
中科院分区：
文献类型：
--
作者：
Mfuh AM;Doyle JD;Chhetri B;Arman HD;Larionov OV
本文报道了一种简单的，无金属和添加剂的，光诱导的卤代芳烃硼化反应，包括富电子的氟代芳烃，以及芳基铵盐直接硼酸。这种硼基化方法具有广泛的范围和官能团耐受性。我们表明，它可以进一步扩展到硼酸酯，并进行克规模以及流动条件下。
We report herein a simple, metal- and additive-free, photoinduced borylation of haloarenes, including electron-rich fluoroarenes, as well as arylammonium salts directly to boronic acids. This borylation method has a broad scope and functional group tolerance. We show that it can be further extended to boronic esters, and carried out on gram scale as well as under flow conditions.