APPLICATION IN BIOSYNTHETIC-STUDIES OF C-13 ISOTOPE SHIFTS IN INFRARED SPECTROSCOPY
APPLICATION IN BIOSYNTHETIC-STUDIES OF C-13 ISOTOPE SHIFTS IN INFRARED SPECTROSCOPY
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DOI：
10.1039/c39760000571
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发表时间：
1976-01-01
影响因子：
--
通讯作者：
OMURA, S
中科院分区：
文献类型：
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作者：
AJISAKA, K;TAKESHIMA, H;OMURA, S
在由95%富集的[1- 13 C]乙酸钠制备的卡那霉素D的红外光谱中，通过13 C同位素位移，证明卡那霉素D [由村山链霉菌合成]中的氰化物C原子来源于乙酸羧基-C原子。
The cyanide C atom in kinamycin D [synthesized by Streptomyces murayamaensis] was shown to originate from the acetate carboxy-C atom by 13C isotope shifts in the IR spectra of kinamycin D prepared from 95% enriched sodium [1-13C]acetate.