Impact of Specifically Shaped Plasmonic Gold Nanoparticles and a Double Cathode Interfacial Layer on the Performance of Conducting Polymer-Based Photovoltaics
Impact of Specifically Shaped Plasmonic Gold Nanoparticles and a Double Cathode Interfacial Layer on the Performance of Conducting Polymer-Based Photovoltaics
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DOI：
10.1021/acsanm.8b01269
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发表时间：
2018-09
影响因子：
5.9
通讯作者：
Ashish Singh;A. Dey;P. Iyer
中科院分区：
文献类型：
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作者：
Ashish Singh;A. Dey;P. Iyer
系统地建立了特殊形状等离子体金纳米粒子（AuNPs）及其与双阴极界面层的联合作用，以提高聚（3-己基噻吩）：(6,6)-苯基- c61 /71-丁酸甲酯（P3HT:PC61/71BM）基聚合物太阳能电池（PSCs）的功率转换效率（PCE）。两种不同的供体-受体共混聚合物，P3HT:PC61BM和P3HT:PC71BM，在这里与BPhen和BCP一起作为传统lifal阴极触点的缓冲层。首先，分别合成了四种特定形状的aunp，即CTAB覆盖的金纳米棒（AuNRs）、金纳米球（AuNSs）、金纳米椭圆（AuNOs）和金纳米分支（AuNBs），并与聚（3,4-乙烯二氧噻吩）：聚苯乙烯磺酸盐（PEDOT:PSS）空穴输运层共混，得到了四种新型的纳米粒子掺杂空穴注入层，并系统地分析了它们对P3HT: pcdm基聚合物光伏器件性能的影响。所合成的纳米颗粒是…
Specifically shaped plasmonic gold nanoparticles (AuNPs) and their combined effect with the double cathode interfacial layer for increasing the power conversion efficiency (PCE) of poly(3-hexylthiophene):(6,6)-phenyl-C61/71-butyric acid methyl ester (P3HT:PC61/71BM)-based polymer solar cells (PSCs) are methodically established. Two diverse donor–acceptor blend polymers, P3HT:PC61BM and P3HT:PC71BM, were used here along with BPhen and BCP as the buffer layers of the conventional LiF:Al cathode contact. Initially, four specifically shaped AuNPs, viz., CTAB capped gold nanorods (AuNRs), gold nanospheres (AuNSs), gold nano-ovals (AuNOs), and gold nanobranches (AuNBs) were separately synthesized and blended along with a poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) hole transporting layer to obtain four novel nanoparticle-doped hole injecting layers, and their effect on P3HT:PCBM-based polymer photovoltaic device performance was methodically analyzed. The synthesized nanoparticles were ch...