[NH3(CH2)6NH3][P2V5O17]·3.83H2O: A new 3D Organic‐templated Vanadophosphate with Extra‐large 16‐Membered Ring Constructed from Nanosized P–O–V Wheels
[NH3(CH2)6NH3][P2V5O17]·3.83H2O: A new 3D Organic‐templated Vanadophosphate with Extra‐large 16‐Membered Ring Constructed from Nanosized P–O–V Wheels
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DOI：
10.1002/zaac.200900467
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发表时间：
2010-01
期刊：
影响因子：
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通讯作者：
Zhibin Zhang;Yan Xu;Leizhi Zheng;Dunru Zhu
中科院分区：
文献类型：
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作者：
Zhibin Zhang;Yan Xu;Leizhi Zheng;Dunru Zhu
以NH 2（CH 2）6 NH 2为模板剂合成了一种新型的三维多孔钒磷酸盐[NH3（CH 2）6 NH3][P2 V5 O 17]·3. 83 H2O（1），并通过单晶结构分析、X射线衍射、红外光谱、热重分析和粉末XRD对其进行了表征。单晶分析表明，化合物1呈立方体形状结晶，空间群为Imm，晶胞尺寸：a = B = c = 26.5068（8）A，V = 18624.0（10）A3，Z = 24。结构精修表明1的无机骨架由纳米级P-O-V轮构成。
A new porous 3D vanadophosphate, [NH3(CH2)6NH3][P2V5O17]·3.83H2O (1) is synthesized by using NH2(CH2)6NH2 as template, and characterized by single crystal structural analysis, X-ray diffraction, IR spectroscopy, TG analysis, and powder XRD. Single crystal analysis shows that compound 1 crystallizes in cubic shape, space group Imm with cell dimensions: a = b = c = 26.5068(8) A, V = 18624.0(10) A3, Z = 24. Structural refinement indicates that the inorganic framework of 1 is constructed from nanosized P–O–V wheels.