Selective oxidation of primary silyl ethers and its application to the synthesis of natural products

Selective oxidation of primary silyl ethers and its application to the synthesis of natural products
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DOI:
10.1016/s0040-4039(99)00956-9
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发表时间:
1999-07-09
影响因子:
1.8
通讯作者:
Godfroid, JJ
Godfroid, JJ
中科院分区:
化学4区
文献类型:
--
作者:
Rodríguez, A;Nomen, M;Godfroid, JJ

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伯TMS或TES醚,在仲TMS或TES醚的存在下,在Swern条件下被选择性地氧化成相应的醛。已经实现了各种天然产物的关键中间体的短合成。(C)1999爱思唯尔科技有限公司。保留所有权利。
Primary TMS or TES ethers, in the presence of secondary TMS or TES ethers, are selectively oxidized to the corresponding aldehydes under Swern conditions. A short synthesis of key intermediates towards various natural products has been achieved. (C) 1999 Elsevier Science Ltd. All rights reserved.