Arrhenius Parameters for the Reactions of O Atoms with Some Alkynes in the Range 300–1300 K

Arrhenius Parameters for the Reactions of O Atoms with Some Alkynes in the Range 300–1300 K
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O 原子与某些炔烃在 300–1300 K 范围内反应的阿伦尼乌斯参数

DOI:
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发表时间:
1983
期刊:
影响因子:
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通讯作者:
C. Wellmann
C. Wellmann
中科院分区:
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文献类型:
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作者:
K. Homann;C. Wellmann

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在300 < T < 1300 K的温度范围内,测量了放电流动体系中氧原子与乙炔(1)、丙炔(2)、1-丁二炔(3)、1-丁烯-3-炔(4)和1-丁炔(5)的反应速率。- 相应的双分子速率常数的Arrhenius表达式为: 炔类化合物的活化能与电离势之间存在相关性。
The rates of the reactions of oxygen atoms with acetylene (1), propyne (2), 1–3-butadiyne (3), 1-buten-3-yne (4), and 1-butyne (5) in a discharge flow system have been measured in the temperature range 300 < T < 1300 K. — The Arrhenius expressions for the respective bimolecular rate constants are There is a correlation between the activation energies and the ionization potentials of the alkynes.