Interface identification by non-local autoionization transitions

Interface identification by non-local autoionization transitions
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DOI:
10.1039/b602019d
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发表时间:
2006-01-01
影响因子:
3.3
通讯作者:
Hergenhahn, Uwe
Hergenhahn, Uwe
中科院分区:
化学2区
文献类型:
--
作者:
Barth, Silko;Marburger, Simon;Hergenhahn, Uwe

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We use an autoionization process that involves ultrafast energy transfer to neighbouring sites to characterize the formation of NeAr van der Waals bonds in clusters formed by a coexpansion of both gases. This autoionization process, the so-called interatomic or intermolecular coulombic decay (ICD), is ubiquitous in weakly bonded systems. The energy of the electron being emitted in the ICD process is shown to be characteristic of the two neighbouring entities and is therefore suggested as a new means for structural investigation, such as interface identification, of weakly bonded complexes.