Silver-catalyzed enantioselective carbon dioxide incorporation into bispropargylic alcohols.
Silver-catalyzed enantioselective carbon dioxide incorporation into bispropargylic alcohols.
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DOI：
10.1021/ja1007118
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发表时间：
2010-03
影响因子：
15
通讯作者：
Shunsuke Yoshida;K. Fukui;S. Kikuchi;T. Yamada
中科院分区：
文献类型：
--
作者：
Shunsuke Yoshida;K. Fukui;S. Kikuchi;T. Yamada
醋酸银与手性席夫碱配体的组合催化剂体系实现了不对称二氧化碳与双丙醇的不对称结合，得到了相应的对映体过量的环碳酸酯。
The combined catalyst system of silver acetate with a chiral Schiff base ligand achieved asymmetric carbon dioxide incorporation into bispropargylic alcohols with desymmetrization to afford the corresponding cyclic carbonates with good-to-excellent enantiomeric excesses.