Platinum(ii)-catalyzed selective para C-H alkoxylation of arylamines through a coordinating activation strategy.
Platinum(ii)-catalyzed selective para C-H alkoxylation of arylamines through a coordinating activation strategy.
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DOI：
10.1039/c8ob02942c
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发表时间：
2019-01
影响因子：
3.2
通讯作者：
Jiabin Shen;Jun Xu;H. Cai;Chao Shen;Pengfei Zhang
中科院分区：
文献类型：
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作者：
Jiabin Shen;Jun Xu;H. Cai;Chao Shen;Pengfei Zhang
报道了一种通过配位活化策略将烷氧基选择性地安装到芳胺帕拉上的高效方法。各种底物都是兼容的，提供相应的产品在良好的优秀的产量。这一策略为不对称芳醚的合成提供了一种有效而实用的解决方案。建议采用自由基途径机制进行转化。
A highly efficient method to selectively install alkoxy onto the para position of arylamines via a coordinating activation strategy has been reported. Various substrates are compatible, providing the corresponding products in good to excellent yields. This strategy gives an efficient and practical solution for the synthesis of unsymmetrical aryl ethers. A free radical pathway mechanism is advised for transformation.