Bisurea-Functionalized Macrocycles: Synthesis and Halide Anion-Response
Bisurea-Functionalized Macrocycles: Synthesis and Halide Anion-Response
复制标题
双脲官能化大环化合物：合成和卤化物阴离子响应
DOI：
10.6023/cjoc201209006
复制
发表时间：
2013
影响因子：
1.9
通讯作者：
Li Yi
中科院分区：
文献类型：
--
作者：
Chen Jinping;Zeng Yi;Yu Tianjun;Li Yi
通过逐步偶联方法合成了氧代双脲官能化的大环化合物，环1、环2和环3。吸收光谱研究表明，环2和环3与卤阴离子的结合比例为1∶1，结合常数为10~10
Oxo-bisurea-functionalized macrocycles, cycle 1, cycle 2, and cycle 3, were synthesized by a stepwise coupling approach. Absorption studies reveal that cycle 2 and cycle 3 can bind with halide anions in a 1∶1 stoichiometry with binding constants of 10~10