Efficient and highly selective iron-catalyzed reduction of nitroarenes

Efficient and highly selective iron-catalyzed reduction of nitroarenes
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DOI:
10.1039/c1cc13728j
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发表时间:
2011-01-01
影响因子:
4.9
通讯作者:
Beller, Matthias
Beller, Matthias
中科院分区:
化学2区
文献类型:
--
作者:
Jagadeesh, Rajenahally V.;Wienhoefer, Gerrit;Beller, Matthias

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碳载铁-菲咯啉配合物的热解导致高度选择性的催化剂,用于将结构不同的硝基芳烃还原为苯胺,产率为90-99%。证明了硝基还原的优良化学选择性。
Pyrolysis of iron-phenanthroline complexes supported on carbon leads to highly selective catalysts for the reduction of structurally diverse nitroarenes to anilines in 90-99% yields. Excellent chemoselectivity for the nitro group reduction is demonstrated.