Photocatalytic oxidation of hydrocarbons by a bis-iron(III)-μ-oxo Pacman porphyrin using O2 and visible light
Photocatalytic oxidation of hydrocarbons by a bis-iron(III)-μ-oxo Pacman porphyrin using O2 and visible light
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DOI：
10.1021/ja058731s
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发表时间：
2006-05-24
影响因子：
15
通讯作者：
Nocera, Daniel G.
中科院分区：
文献类型：
--
作者：
Rosenthal, Joel;Luckett, Thomas D.;Nocera, Daniel G.
以可见光和分子氧为末端氧化剂和氧原子源，以缺电子的Pacman卟啉(DPDF)Fe2O为催化剂，催化氧化碳氢化合物的C-−氢键。光催化反应在温和的条件下(环境温度和压力)进行，不需要外部助还原剂。
The C−H bonds of hydrocarbons are oxidized catalytically by the electron-deficient Pacman porphyrin, (DPDF)Fe2O, using visible light and molecular oxygen as the terminal oxidant and oxygen atom source. The photocatalytic reactions proceed under mild conditions (ambient temperature and pressure) without the need for an external co-reductant.