Handbook of Industrial Crystallization. Third edition. Edited by Allan S. Myerson, Deniz Erdemir and Alfred Y. Lee. Cambridge University Press, 2019. Pp. 538. Price GBP 145 (hardcover). ISBN 9780521196185.
Handbook of Industrial Crystallization. Third edition. Edited by Allan S. Myerson, Deniz Erdemir and Alfred Y. Lee. Cambridge University Press, 2019. Pp. 538. Price GBP 145 (hardcover). ISBN 9780521196185.
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工业结晶手册。
DOI：
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发表时间：
2020
影响因子：
6.1
通讯作者：
K. Benz
中科院分区：
文献类型：
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作者：
K. Benz
这本手册是关于工业结晶主题的第三版；第一版于1993年由剑桥大学出版社出版。本书共16章（527页），由不同的作者撰写，涵盖了工业结晶的最基本和应用主题。第1-6章涉及工业结晶这一特殊领域的基本和基本方面。晶体生长在这里是指从不同类型的溶液中生长。第1章：解和解的性质。第一章提供了与晶体生长过程有关的重要双组分和多组分溶液的很好的综述。在各种溶剂中的溶解度以及无机组分在水中溶解度的巨大差异是突出的。其他主题是溶解度在混合溶剂，过饱和和亚稳态。基本热性质影响活性结晶器温度变化过程中的能量传递。第二章：晶体和晶体生长。这包含了晶体的基本概念和七个晶体系统和布拉瓦晶格的简短介绍。提到了完美晶体中的一些缺陷，如Frenkel缺陷和Schottky缺陷。为了帮助读者理解晶体生长现象的原理，应该给缺陷更多的讨论空间。缺陷通常对晶体的质量和尺寸起着重要的作用。第3章：晶体成核，对晶体的形态进行了广泛而深入的描述，包括晶体预期形状的形态预测。本章主要讨论溶液的结晶。给出了均相成核和非均相成核形成核的基础。重点讨论了二次成核的起源、成核现象、成核动力学和成核控制。第四章：杂质和添加剂对结晶的影响。提高纯化和所得晶体质量的策略是重要的。作者详细叙述了外来物质对晶体生长速度和晶体性能的影响。第五章：分子模拟在结晶中的应用。描述了不同的计算成核方法来分析晶体结构，并预测形貌和多态性。此外，这些方法还用于从x射线粉末衍射数据中求解晶体结构。第六章：用人口平衡模型分析结晶过程。为了在结晶过程中获得适当的粒度分布，作者使用了种群平衡的数学模型。第七章：工业结晶器的选择与设计。作者描述了与几种结晶方法有关的性能标准，这可能会导致结晶器的设计。结晶器的配置对产品质量有很大影响。概述了结晶器的主要类型及其特点。第八章：降水过程。作者描述了非常小晶体的复杂沉淀过程。颗粒浓度通常在每立方厘米1011至1017个颗粒之间，晶体尺寸在0.1至100毫米之间。讨论了提供降水驱动力的物理和热力学性质。原生成核和次生成核动力学起着重要的作用。第九章：熔融结晶。熔体生长的好处是传热是主要的过程，而在溶液生长中，传质是最重要的
This handbook is the third edition on the topic Industrial Crystallization; the first edition was published by Cambridge University Press in 1993. The book contains 16 chapters (527 pages) written by different authors and covers most basic and applied topics of industrial crystallization. Chapters 1–6 deal with basic and fundamental aspects in the special field of industrial crystallization. Crystal growth means here in particular growth from various types of solutions. Chapter 1: Solutions and Solution Properties. The first chapter provides a very good survey of important twoand multicomponent solutions related to crystal growth processes. A wide variety of solubility in various solvents as well as large differences of solubility of inorganic components in water is highlighted. Other topics are solubility in mixed solvents, supersaturation and metastability. Fundamental thermal properties affect the energy transfer during the change of temperature in active crystallizers. Chapter 2: Crystals and Crystal Growth. This contains basic concepts of crystals and a short introduction to the seven crystal systems and Bravais lattices. Mentioned are some defects in perfect crystals like Frenkel and Schottky defects. More space should have been given to the discussion of defects in order to help readers understand the principles of crystal growth phenomena. Defects often play a major part in the quality and size of crystals. A broad intense description of morphology of crystals, including morphological prediction of the expected shape of crystals, is given Chapter 3: Crystal Nucleation. This chapter is concentrated on crystallization from solutions. A basis for the formation of a nucleus by homogeneous and heterogeneous nucleation is given. Intensively discussed are the origin of secondary nucleation, its nucleation phenomena, nucleation kinetics and control of nucleation. Chapter 4: The Influence of Impurities and Additives on Crystallization. Strategies to improve the purification and the quality of the resulting crystals are important. The authors describe in detail the influence of foreign species on the growth rate and crystal properties. Chapter 5: Molecular Modeling Applications in Crystallization. Described are different computational nucleation methods to analyse crystal structures, and to predict morphology and polymorphism. Moreover, these methods are used to solve crystal structures from X-ray powder diffraction data. Chapter 6: Crystallization Process Analysis by Population Balance Modeling. In order to obtain e.g. an appropriate particle size distribution within the crystallization process, the authors use mathematical models of population balance. Chapter 7: Selection and Design of Industrial Crystallizers. The authors describe performance criteria in connection with several crystallization methods, which may lead to the design of crystallizers. The configurations of crystallizers strongly influence the product quality. An overview of the main crystallizer types with their characteristics is given. Chapter 8: Precipitation Processes. The authors describe the complex process of precipitation with very small crystals. The particle concentration is usually between 1011 and 1017 particles per cubic centimetre and the crystal size between 0.1 and 100 mm. Physical and thermodynamic properties providing the driving force for precipitation are discussed. The kinetics of primary and secondary nucleation play an important role. Chapter 9: Melt Crystallization. The benefit of melt growth is that heat transfer is the dominating process, whereas in solution growth mass transfer is the most important ISSN 1600-5767