Synthesis and reactivity of a conveniently prepared two-coordinate bis(amido) nickel(II) complex
Synthesis and reactivity of a conveniently prepared two-coordinate bis(amido) nickel(II) complex
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DOI：
10.1039/c2cc32974c
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发表时间：
2012-01-01
影响因子：
4.9
通讯作者：
Tilley, T. Don
中科院分区：
文献类型：
--
作者：
Lipschutz, Michael I.;Tilley, T. Don
制备了严格的二配位镍（II）双（氨基）配合物，并描述了其对各种小分子的反应性。Ni[N（SiMe3）（DIPP）]（2）与DMAP和乙腈反应生成T型三配位配合物，初步结果表明Ni[N（SiMe3）（DIPP）]（2）是室温下烯烃与仲硅烷硅氢化反应的催化剂。
A strictly two-coordinate nickel(II) bis(amido) complex has been prepared and its reactivity towards a variety of small molecules is described. Ni[N(SiMe3)(DIPP)](2) reacts with DMAP and acetonitrile to form T-shaped three-coordinate complexes, and preliminary results show that Ni[N(SiMe3)(DIPP)](2) is a catalyst for the hydrosilation of olefins with secondary silanes at ambient temperature.