Improving the tribological and mechanical properties of polyimide composites by incorporating functionalized graphene

Improving the tribological and mechanical properties of polyimide composites by incorporating functionalized graphene
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通过掺入功能化石墨烯提高聚酰亚胺复合材料的摩擦学和机械性能

DOI:
10.1177/0954008319847260
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发表时间:
2019-05
影响因子:
2.1
通讯作者:
Lu Shaorong
Lu Shaorong
中科院分区:
化学4区
文献类型:
--
作者:
Li Yuqi;Zhang Qiu;Ruan Hong;Li Fengan;Xu Xu;Huang Xiaohua;Lu Shaorong

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To explore the effect of added graphene sheets (GNs) and added perylene-3,4,9,10-tetracarboxylic dianhydride (PTCDA) on the tribological and mechanical performances of polyimide (PI) matrix, GNs and PTCDA reinforced PI-based composites were synthesized via the blending method. The tribological properties of GNs/PTCDA/PI (GAPI) composites with different weight ratios of GNs and PTCDA under dry sliding, deionized water lubrication, and kerosene lubrication were comparatively investigated. A synergism was found between GNs and PTCDA; this synergism endowed filled PI composites with a lower friction coefficient and showed an improved wear rate under different lubrication conditions, especially when the weight ratio of GNs and PTCDA was 1:1 (GAPI-1). Under dry sliding, deionized water lubrication, and kerosene lubrication, the friction coefficient of GAPI-1 composites decreased by 41.1%, 70%, and 35.7%, respectively, while the wear rate decreased by 39%, 50%, and 25.1%, respectively. Meanwhile, the tensile strength, tensile modulus, and the elongation at break of GAPI-1 films increased by 40.8%, 51.3%, and 49.2%, respectively, relative to those of pure PI. We anticipate that this work can be used to exploit a simple and effective method for preparing materials for bearings and transmission parts that possess good tribological properties under harsh lubrication conditions.
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