Detection of weak hydrogen bonding to fluoro and nitro groups in solution using H/D exchange.
Detection of weak hydrogen bonding to fluoro and nitro groups in solution using H/D exchange.
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DOI：
10.1039/c5ob02360b
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发表时间：
2016-02
影响因子：
3.2
通讯作者：
C. R. Shugrue;J. R. DeFrancisco;A. J. Metrano;B. Brink;R. Nomoto;B. Linton
中科院分区：
文献类型：
--
作者：
C. R. Shugrue;J. R. DeFrancisco;A. J. Metrano;B. Brink;R. Nomoto;B. Linton
氢/氘（H/D）交换可以是用于测量与中性有机硝基和氟基团的氢键强度的灵敏技术。与合适的对照相比，较慢的反应速率表明存在氢键，尽管相当弱。
Hydrogen/deuterium (H/D) exchange can be a sensitive technique for measuring the strength of hydrogen bonding to neutral organic nitro and fluoro groups. The slower rates of reaction in comparison to suitable controls suggest that hydrogen bonding is present, albeit rather weak.