Green photochemistry: Production of fine chemicals with sunlight

Green photochemistry: Production of fine chemicals with sunlight
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绿色光化学:利用阳光生产精细化学品

DOI:
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发表时间:
2006
期刊:
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通讯作者:
J. Mattay
J. Mattay
中科院分区:
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文献类型:
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作者:
M. Oelgemöller;C. Jung;J. Mattay

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摘要在中等浓度太阳光照射条件下,研究了三个光化学反应:萘醌与丁醛的光酰化反应和染料敏化的香茅醇和1,5-二羟基萘的光氧化反应。所有的反应都很容易在数克到千克的规模上进行,使用廉价的商业原料,并产生了重要的关键中间体的工业应用。
Abstract Three photochemical reactions were investigated under solar irradiation conditions with moderately concentrated sunlight: the photoacylation of naphthoquinone with butyraldehyde and the dye-sensitized photooxygenations of citronellol and 1,5-dihydroxynaphthalene, respectively. All reactions were easily performed on multigram-to-kilogram scales using cheap and commercially available starting materials, and yielded important key intermediates for industrial applications.