Enantioselective Glucosylation of (R,S)-1-Phenylethanol by the Cultured Suspension Cells of Higher Plants.

Enantioselective Glucosylation of (R,S)-1-Phenylethanol by the Cultured Suspension Cells of Higher Plants.
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高等植物培养悬浮细胞对 (R,S)-1-苯乙醇的对映选择性糖基化。

DOI:
10.1246/cl.1996.719
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发表时间:
1996
期刊:
影响因子:
1.6
通讯作者:
T. Hirata
T. Hirata
中科院分区:
化学4区
文献类型:
--
作者:
Y. Lee;D. I. Ito;K. Koya;S. Izumi;T. Hirata

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(R,S)-1-Phenylethanol and its acetate were transformed into their β-D-glucopyranoside by the cultured suspension cells of Nicotiana tabacum and Catharanthus roseus. The glucosylation with the green N. tabacum cells occurred enantioselectively to give the glucoside of the (S)-alcohol, while the biotransformation with the white N. tabacum cells and C. roseus cells gave preferentially the glucoside of the (R)-alcohol.