Analysis of the ?1 and ?3 absorption bands of 32S16O2

Analysis of the ?1 and ?3 absorption bands of 32S16O2
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32S16O2 的 ?1 和 ?3 吸收带分析

DOI:
10.1016/0022-2852(84)90281-9
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发表时间:
1984
影响因子:
1.4
通讯作者:
G. Ushakova
G. Ushakova
中科院分区:
物理与天体物理4区
文献类型:
--
作者:
G. Guelachvili;O. Ulenikov;G. Ushakova

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用傅里叶变换干涉仪在高分辨率下研究了32S16O2在1055-2000 cm−1之间的光谱。分析了两个基带:a型带ν3和b型带ν1。对这些带的仔细分析得到了属于振动态(000)、(100)和(001)的一组更广泛和更精确的转动能级。根据这组改进的振动能,得到了(000)、(100)和(001)态的转动常数和离心常数。
The spectrum of32S16O2between 1055 and 2000 cm−1has been investigated under high resolution with a Fourier transform interferometer. Two fundamental bands have been analyzed; theA-type bandν3and theB-type bandν1. A careful analysis of these bands has led to the availability of an extended and more precise set of rotational levels belonging to the vibrational states (000), (100) and (001). From this set of improved vibrational energies, rotational and centrifugal constants for the states (000), (100), and (001) have been obtained.