Nickel-catalyzed Tishchenko reaction via hetero-nickelacycles by oxidative cyclization of aldehydes with nickel(0) complex.
Nickel-catalyzed Tishchenko reaction via hetero-nickelacycles by oxidative cyclization of aldehydes with nickel(0) complex.
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DOI：
10.1039/b926866a
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发表时间：
2010-05
影响因子：
4.9
通讯作者：
S. Ogoshi;Y. Hoshimoto;M. Ohashi
中科院分区：
文献类型：
--
作者：
S. Ogoshi;Y. Hoshimoto;M. Ohashi
发展了一种Ni（0）催化的Tishchenko反应，该反应可用于多种脂肪醛（伯、仲、叔）和芳香醛的合成。该反应可能通过杂镍镧中间体进行。
A Ni(0)-catalyzed Tishchenko reaction which can be applied to a variety of aliphatic aldehydes (primary, secondary, tertiary) and aromatic aldehydes was developed. The reaction might proceed via a hetero-nickelacycle intermediate.