The catalysis gold rush: New claims
The catalysis gold rush: New claims
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DOI：
10.1002/anie.200502735
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发表时间：
2005-01-01
影响因子：
16.6
通讯作者：
Hashmi, ASK
中科院分区：
文献类型：
--
作者：
Hashmi, ASK
金的均相催化并不新鲜：其根源至少可以追溯到 70 年前。[1]催化剂非常强劲；在大多数情况下，不需要排除水或氧气。[1, 2] 然而，截至 2003 年底，该领域的出版物很少。在对当年的均相金催化反应的回顾中，[1] 我总结道：“我相信这些发展将在不久的将来加速，并且大多数在均相过渡金属催化领域工作的人也将给金一个机会 定期”。显然，许多研究者都有同样的想法：自2004年以来，可以观察到金配合物均相催化的出版物急剧且持续增加。在这里，我想“强调”这个新兴领域中一些令人兴奋的新“主张”（不包括其他地方最近审查的方面）。[3-5]
Homogeneous catalysis by gold is not new: the roots reach back at least 70 years.[1] The catalysts are quite robust; an exclusion of water or oxygen in most cases is not necessary.[1, 2] Nevertheless, only very few publications in this field appeared up to the end of the year 2003. In a review on homogenous goldcatalyzed reactions from that year,[1] I concluded with the sentence “I am confident that these developments will accelerate in the near future, and that most people working in the field of homogeneous transition-metal catalysis will also give gold a chance on a regular basis”. Obviously many investigators had the same thought: since 2004 a sharp and continuing increase of the publications on homogeneous catalysis by gold complexes can be observed. Here, I would like to “highlight” some of the exciting new “claims” in this emerging field (excluding aspects recently reviewed elsewhere).[3–5]