IN-SITE POLYMERIZATION OF TETRAHYDROFURAN ON HPA/MCM-48
IN-SITE POLYMERIZATION OF TETRAHYDROFURAN ON HPA/MCM-48
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发表时间：
2002
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通讯作者：
Duan Xue
中科院分区：
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作者：
Duan Xue
提出了一种新型无机有机纳米复合结构的设计。利用纳米尺寸的孔和孔壁以及聚合所需的温和条件，HPA改性的MCM 48被提议作为新型无机有机纳米复合材料结构的无机组分。制备了HPA/MCM 48，并通过XRD、TEM和FT IR方法对其进行了表征，并将其用作四氢呋喃原位聚合的催化剂。 FT IR 结果提供的证据表明发生了这种原位聚合。
The design of a novel inorganic organic nanocomposite structure was put forward. By making use of the nano sized pores and pore walls, and also the mild conditions required for polymerization, MCM 48 modified by HPA was proposed as the inorganic component of the novel inorganic organic nanocomposite structure. HPA/MCM 48 was prepared, and characterized by XRD, TEM and FT IR methods, and was used as the catalyst in in situ polymerization of tetrahydrofuran. Evidences provided by the FT IR results identified that this in situ polymerization occurred.