Ni−Re (Nickel-Rhenium) system

Ni−Re (Nickel-Rhenium) system
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Ni−Re(镍铼)系统

DOI:
10.1007/bf02880520
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发表时间:
1985
期刊:
Bulletin of Alloy Phase Diagrams
影响因子:
--
通讯作者:
P. Nash
P. Nash
中科院分区:
--
文献类型:
--
作者:
A. Nash;P. Nash

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图1所示的评估Ni-Re相图是基于[70 Sav]和[72 Sav]的工作。Ni-Re系统的早期工作由[31 Moe]完成,他发现Ni和Re在高温下形成合金,[34 Fin],[36 You]和[51 Net]从水溶液中电解沉积Ni-Re合金。[54 Pog]使用X射线、热分析和金相分析研究了Ni-Re合金,在该系统中没有发现化合物。[54 Pog]在1600~ 29.8at. Re,得到(Ni)和(Re)的两种固溶体。他们还发现Re在(Ni)中具有广泛的固溶度,其随温度从29.8at.% Re为1600~约8.4原子% Re为800时,Ni在(Re)中的溶解度约为58 at.%倪然而,[54 Pog]提供了(Ni)固溶体的固相线和液相线的数据,仅在固相线中显示最小值,这与相规则不一致。
The assessed Ni-Re phase diagram shown in Fig. 1 has been based on the work of [70Sav] and [72Sav]. Early work on the Ni-Re system was done by [31Moe], who found that Ni and Re form alloys at high temperatures, and by [34Fin],[36You], and [51Net], who deposited Ni-Re alloys electrolytically from aqueous solutions.[54Pog] studied Ni-Re alloys using X-ray, thermal, and metallographic analyses and found no compounds in this system.[54Pog] found a peritectic reaction at 1600~ and 29.8 at.% Re, yielding the two solid solutions of (Ni) and (Re). They also found extensive solid solubility for Re in (Ni), which decreased rapidly with temperature from 29.8 at.% Re at 1600~ to about 8.4 at.% Re at 800~ the solubility of Ni in (Re) was taken to be about 58 at.% Ni. However,[54Pog] presented data for both the solidus and the liquidus of the (Ni) solid solutions showing a minimum in the solidus only, which is inconsistent with the phase rule.