Molecular Thermodynamics of Adsorption

用分子理论研究了气体在固体表面的吸附。主要的重点是了解吸附平衡中表面结构的影响和吸附-吸附相互作用之间的关系。两个相辅相成的冲刺正在进行。第一部分是多组分体系吸附平衡理论的发展和应用。特别有趣的是表面结构对吸附溶液中非理想行为的影响。第二个推力与基于分子的计算机模拟吸附层有关。高度结构化表面上的层。这项工作将扩展到多组分体系和多层吸附。

Adsorption of gases on solid surfaces is studied using molecular theory. The primary focus is on understanding the relationship between effects of surface structure and adsorbate-adsorbate interactions in adsorption equilibria. Two complementary thrusts are pursued. The first concerns the development and application of theories of adsorption equilibria for multicomponent systems. Of particular interest is the influence of surface structure on non-ideal behavior in adsorbed solutions. The second thrust is concerned with the molecular based computer simulation of adsorbed layers. The layers on highly structured surfaces. This work will be extended to multicomponent systems and multilayer adsorption.