Infrared and Microwave Spectroscopic Studies of Inter- molecular Interactions

这项研究，在实验物理化学 计划，旨在了解能量学和动力学 包括复合物和簇的弱结合分子。 这项研究将获得红外和微波光谱的 各种弱结合的分子。 将对数据进行分析 产生分子的几何形状，振动频率的变化 以及诸如力矩和场梯度的电子性质。 大部分工作将针对簇族， 含有水和乙炔的络合物。 电子 稳定分子在激发振动和 电子状态也将被测量，以帮助 描述了松散结合物种的长程相互作用。

This research, in the Experimental Physical Chemistry Program, is aimed at understanding the energetics and dynamics of weakly bound molecules including complexes and clusters. The research will obtain infrared and microwave spectra of a variety of weakly bound molecules. The data will be analyzed to yield molecular geometries, shifts in vibational frequencies and electronic properties such as moments and field gradients. Much of the work will be directed at families of clusters and complexes containing water and acetylene. Electronic properties of stable molecules in excited vibrational and electronic states will also be measured, in order to help describe long range interactions of loosely bound species.