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NSF Young Investigator/Synchrotron Fragmentation Pathway of Small Molecules

NSF Young Investigator/Synchrotron Fragmentation Pathway of Small Molecules
NSF 青年研究员/小分子同步加速器碎裂途径
批准号:
9257434
负责人:
Tricia Ferrett
金额:
$31.25万
依托单位:
依托单位国家:
美国
项目类别:
Continuing Grant
财政年份:
1992
资助国家:
美国
项目状态:
已结题
起止时间:
1992-09-01 至 1999-08-31

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中文摘要
翻译
特里西娅·A费雷特(卡尔顿学院),是一个NSF的收件人 实验物理学研究青年研究者奖 化学.她的项目包括使用同步加速器 辐射诱导小分子碎裂, 激发其核心电子。费雷特教授将召集 飞行时间质谱仪和定时电路, 允许同时检测和能量表征 两种或多种碎片产物。通过控制事件 光子能量和被照射分子的类型,教授。 费雷特将阐明碎裂的系统特征 途径。这一点很重要,因为核心的激发 电子作为碎裂的起始点, 与低能量光子激活的途径不同, 对新途径的详细了解 提高对化学键的理解。 %%% Tricia A.费雷特(卡尔顿学院),将使用X射线, 诱导小分子分解。通过测量 同时释放几个碎片的能量, 将发展一个详细的方式, X射线的吸收导致分子 破坏要研究的特定分子具有一般性, 大气化学和化学的重要性. 催化表面
英文摘要
Tricia A. Ferrett (Carleton College), is the recipient of A NSF Young Investigator award for studies in Experimental Physical Chemistry. Her project involves the use of synchrotron radiation to induce fragmentation of small molecules by excitation of their core electrons. Prof. Ferrett will assemble a time-of-flight mass spectrometer and timing circuitry to permit simultaneous detection and energy characterization of two or more fragmentation products. By controlling the incident photon energy and the type of molecule to be irradiated, Prof. Ferrett will elucidate systematic features of fragmentation pathways. This is important because excitation of core electrons as a starting point for fragmentation leads to different pathways than those activated by low energy photons, and detailed knowledge of the new pathways translates to an improved understanding of chemical bonds in general. %%% Prof. Tricia A. Ferrett (Carleton College), will use X-rays to induce small molecules to fall apart. By measuring simultaneously the energies of several fragments, Prof. Ferrett will develop an increased understanding of the detailed way in which the absorption of the X-rays leads to molecular disruption. Particular molecules to be studied are of general importance in the chemistry of the atmosphere and chemistry at catalytic surfaces.
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会议论文
Molecular Fragmentation Studies Utilizing Ion-Ion Coincidence Techniques and Synchrotron Radiation
  • 批准号:
    9110614
  • 项目类别:
    Standard Grant
  • 资助金额:
    $1.8万
  • 财政年份:
    1991
  • 负责人:
    Tricia Ferrett
  • 依托单位:
海外基金