RUI: Measurement of Hyperfine Interactions in Small Molecules

9302894塞德伯格这项瑞建议涉及使用高分辨率分子束电共振谱仪测量小分子振动和转动状态序列中的超精细结构。这些光谱将提供改进的超精细相互作用常数的值，并将用于确定每个核位置的电场梯度随核间距离的变化。场梯度将与电子波函数的理论计算得到的场梯度进行比较。

9302894 Cederberg This RUI proposal concerns the measurement of hyperfine structure in sequences of vibrational and rotational states in small molecules using a high-resolution molecular beam electric resonance spectrometer. These spectra will provide improved values for hyperfine interaction constants and will be used to determine the variation with internuclear distance of electric field gradients at each nuclear site. The field gradients will be compared with those obtained from theoretical calculations of electron wave functions.