Synthesis of Porous Hybrid Materials based on Layered Silicates: Functional Intercalates, Separation, and Catalysis (A06)

荷电均质钙钛矿的优化熔融合成允许对膨胀过程进行基本的洞察，并为内外表面的功能化提供了各种方法。基于一维异质结构的渗透膨胀的一般程序使双叠层和Janus型血小板成为可能。间隔物(柱子、纳米颗粒)的插层形成了用于气体分离和催化的微孔材料。该项目探索了功能化胶体层状硅酸盐的应用，这些层状硅酸盐来自各种结构方法。

An optimized melt synthesis of a charge homogenous hectorite allows for fundamental insights into the process of swelling and provides various ways for the functionalization of internal and external surfaces. A general procedure based on osmotic swelling of 1D-heterostructures makes double stacks and Janus-type platelets accessible. Intercalation of spacers (pillars, nanoparticles) creates micropores materials for gas separation and catalysis. This project explores the application of functionalized colloidal layered silicates derived from various methods of structuring.