CAREER: Investigation of Laser-Induced Breakdown Spectroscopy for Analysis of Airborne Particulate Matter

最近和即将出台的颗粒物（PM）的联邦空气污染法规要求开发连续排放监测器，以测量气载颗粒的大小和组成。激光诱导击穿光谱（LIBS）是一种很有前途的方法，用于实时测量尺寸范围为100 nm - 10 nm的主要无机气溶胶颗粒的联合尺寸和组成。这些纳米颗粒已被证明与一系列显著的健康影响有关，包括肺功能下降，哮喘发病率增加，肺组织和结构改变，住院人数增加和过早死亡。在LIBS中，利用高能量脉冲激光在样品介质中产生火花或击穿。 最近在焚烧炉和热处理装置上进行的这项技术的现场试验表明，LIBS测量很好地跟踪了排放趋势，并且可以捕获提取式积分型采样器未观察到的瞬态事件。由于联合颗粒成分和尺寸的可能性，LIBS也是有吸引力的源解析，即，在一个空气脱落的组成指纹的特定颗粒的来源的确定。该提案的主要目标是：1）了解颗粒基质、气体基质以及等离子体尺寸和温度对LIBS测量的联合影响，2）确定使用LIBS进行颗粒测量的尺寸上限和下限，以及最佳激光功率、最佳火花尺寸和温度的变化。各种颗粒尺寸的最佳检测器门延迟和宽度，3）对典型颗粒成分的颗粒/等离子体相互作用进行建模，如前两个目标所实现的，4）对环境气溶胶进行实时、准确、全谱的LIBS测量，职业发展计划包括一个强有力的教育部分，涉及高中学生、高中教师和大学生。有人建议，一些有前途的年轻科学学生之间的摩擦是由于目前的科学问题和主导高中/大学早期的基础科学课程之间缺乏联系。拟议的教育计划涉及创建交互式网络教学工具，使用熟悉的大气现象，如光化学烟雾，臭氧洞，酸雨和空气中悬浮微粒的迁移等插图，教授与真实的问题有关的基本科学概念。当局会从马里兰州大学招聘有兴趣从事教育工作的理工科本科生，协助本地高中的先修课程化学及环境科学教师发展课程，以及编制计算机/网络程式，为先修课程发展互动学习单元。希望这些努力能促进有前途的高中生保持学习科学的动力，而一些有教学能力的大学生可能会有一个有益的经验，激发科学教育的兴趣。我们计划将教育计划与研究计划结合起来，在项目的第四年和第五年将LIBS单元带到学校进行环境气溶胶测量，作为气溶胶课程模块的一部分。

Recent and pending Federal air pollution regulations for particulate matter (PM) require the development of continuous emissions monitors to measure the size and composition of airborne particles. Laser-induced breakdown spectroscopy (LIBS) is a promising method for real-time measurement of joint size and composition of primarily inorganic airborne aerosol particles in the size range 100 nm - 10 nm. These nanoparticles have been shown to be linked to a series of significant health effects, including decreased lung function, increased incidence of asthma, alterations in lung tissue and structure, increased hospital admissions, and premature death. In LIBS, a high-energy pulsed laser is utilized to create a spark, or breakdown, in the sample media. Recent field trials of this technique on incinerators and thermal treatment units show that LIBS measurements follow trends of emissions well and can capture transient events that are not observed by extractive, integrating type samplers. Due to the possibility of joint particle composition and sizing, LIBS also is attractive forsource apportionment, that is, determination of the source of particular particles in an airshed by compositional fingerprinting. The primary objectives of the proposal are:1) to understand the joint influences of the particle matrix, of the gas matrix, and of plasma size and temperature on the LIBS measurement,2) to determine the upper and lower size limits for particle measurements using LIBS, and the variation in optimal laser power, optimum spark size and temperature, and optimum detector gate delay and width for various particle sizes,3) to model the particle / plasma interaction for typical particle compositions, as enabled by the previous two objectives,4) to perform real-time, accurate, full-spectrum LIBS measurements of ambient aerosol, as enabled by the previous three objectives.The career development plan includes a strong educational component involving both high school students, high school teachers, and college students. It is suggested that some of the attrition among promising young science students is due to a perceived lack of connection between current scientific problems and the basic science classes that dominate high school / early college years. The proposed educational plan involves the creation of interactive, web-based teaching tools that use illustrations from familiar atmospheric phenomena such as photochemical smog, the ozone hole, acid rain, and migration of airborne aerosol particles to teach basic science concepts linked to real problems. Undergraduate engineering and science students from the University of Maryland with an interest in teaching would be recruited to assist AP Chemistry and AP Environmental Science teachers from local high schools in curriculum development and computer/web programming to develop interactive learning modules for the AP classes. It is hoped that these efforts promote promising high school students to remain motivated to study science, while some college students with a teaching aptitude may have a rewarding experience that stimulates interest in science education. We plan to tie the education plan with the research plan by bringing the LIBS unit to schools to make ambient aerosol measurements as part of an aerosol curriculum module in the 4th and 5th years of the project.