Investigations of homogeneously catalzyed reactions in micellar solvent systems (A02)

在前人研究成果的基础上，利用胶束溶剂体系，研制出了1-十一醛还原胺化反应混合物。对于未知反应，合理选择最佳相系将是这项工作的重点。在工艺合成过程中，快速有效地选择合适的表面活性剂是基于反应条件的同时优化和催化剂的回收。此外，还将进行详细的动力学研究，以开发适用于反应器设计和过程控制的还原胺化宏观动力学模型。

On the basis of the results from the previous founding periods, a reaction mixture for the reductive amination of 1-undecanal will be formulated by the use of micellar solvent systems. The rational selection of an optimal phase system for an unknown reaction will be the focus of this work. A fast and efficient selection of an appropriate surfactant during the process synthesis is based on the simulta-neous optimization of reaction conditions and catalyst recycling. In addition, detailed kinetic studies will be performed to develop a macrokinetic model for the reductive amination, suitable for reactor design and process control.