Luminescence properties of isolated lanthanide and transition metal complexes (C07)

这个3MET项目研究光致发光异核镧系和过渡金属配合物中的金属-金属相互作用和功能协同性。它研究金属中心的结构和配位。它筛选这些复合物进行可见光到近红外的向下转换和近红外到可见光的向上转换，两者在本质上都是高度合作的。它将结构和发光联系起来，并研究了环境相互作用对非辐射跃迁的影响。它结合了大量选择离子的气相发光研究，溶液和晶体的测量，以及量子化学计算。

This 3MET project investigates metal-metal interactions and functional cooperativity in photoluminescent heteronuclear lanthanide and transition metal complexes. It studies structure and coordination of the metal centers. It screens these complexes for visible to near infrared down conversion and for near infrared to visible up conversion, both of which are highly cooperative in nature. It correlates structure and luminescence, and it investigates the influence of environmental interactions on non-radiative transitions. It com-bines gas phase luminescence studies on mass-selected ions, measurements in solution and on crystals, and quantum-chemical calculations.