Porous compartmentalized multi-catalytic electrospun membranes for reaction cascades in one-pot using ‘Wolf-Lamb’ catalysts (A12)

具有非常高孔隙率和不同孔径的分隔纤维膜和纤维形态将被探索作为一锅串联反应中不相容(Wolf-Lamb类型)催化剂的现场隔离固定化的新型多催化剂载体。该项目第一部分建立的并排和同轴结构为以特定于现场的方式固定多个催化剂提供了独特的机会，并具有大量运输所需的高孔隙率、可升级性和可重复使用等额外优势。这项研究将把实验和计算机模拟结合起来，以做出定量预测，并了解流经几何复杂介质的催化过程。

Compartmentalized fibrous membranes and fiber morphologies with very high porosity and diverse pore size will be explored as novel multi-catalysts carrier for site-isolated immobilisation of incompatible (Wolf-Lamb type) catalysts in one-pot cascade reactions. The side-by-side and coaxial structures established in the first part of the project offer a unique opportunity for immobilisation of multiple catalysts in a site-specific manner with additional advantages of high porosity required for mass transport, upscalability and reusability. The study will combine experiments and computer simulations to make quantitative predictions and to understand the catalytic processes in flows through geometrically complex media.