Design of hierarchically ordered porous materials by two photon polymerisation of resins containing coordination polymers

该项目的目的是通过双光子聚合（2PP）直接组装分级有序的多孔材料。为了实现这一目标，将探索一类新的树脂化合物。在2PP期间结构化的树脂含有纳米多孔MOF纳米颗粒。后者被官能化以允许适当地嵌入聚合物基质中。这种策略允许制造含有纳米孔和大孔的纳米复合材料。所得材料将通过常用方法表征，特别是关于纳米孔的可进入性的吸附测量

Aim of the proposed project is to engineer the direct assembly of hierarchically ordered porous materials by two photon polymerization (2PP). To achieve this, a new class of resin compounds will be explored. The resins, that are structured during the 2PP contain nanoporous MOF nanoparticels. The latter are functionalized to allow the proper embedding in a polymer matrix. This strategy allows the fabrication of nanocomposit materials containing nano- and macropores. The resulting materials will be characterized by common methods, especially sorption measurements with regard to the accessability of the nanopores