Integration of Photoredox-active Complexes in Redox-active Polymers for Light-induced Charging and Discharging by Additional Integrated Molecular Catalysts (B02)

B 02将探索基于不含贵金属的结构单元和氧化还原活性聚合物的PS/PS-CAT之间的光诱导电子转移。将探讨聚合物结构和形态对整体氧化还原级联效率的影响。将进行氧化还原聚合物的光驱动还原充电，并使用PS-CAT二联体将其偶联至AOC。坚固的导电聚合物将被氧化以用PS-CAT二联体为光驱动的HER催化提供燃料。带电的聚合物将通过适当的催化剂或电极放电，从而能够形成聚合物Z-方案。

B02 will explore light-induced electron-transfer between PS/PS-CAT based on noble metal free building blocks and redox-active polymers. Effects of the polymer structure and morphology on the efficiency of the overall redox cascade will be explored. Light driven reductive charging of redox polymers will be performed and coupled to AOC using PS-CAT dyads. Robust conducting polymers will be oxidized to fuel the light driven HER catalysis with PS-CAT dyads. Charged polymers will be discharged by appropriate catalysts or electrodes enabling the development of a polymeric Z-scheme.