Control of Spin States at Metal Centers through Fluorine-Specific Interactions in the Secondary Coordination Sphere (B02)

在这个项目中，我们希望开发在特定位置包含C-F键的配体系统。这种C-F单元将用于在3d金属中心的次级配位层中产生目标氟特异性相互作用，这反过来将控制过渡金属中心的自旋状态。该项目的直接目标是通过外部刺激实现自旋状态的切换。长期目标是通过控制其自旋状态来改变过渡金属中心的反应性。

Within this project, we want to develop ligand systems that contain C-F bonds at specific positions. Such C-F units will be used to generate targeted Fluorine-Specific Interactions in the secondary coordination sphere of 3d metal centers, which in turn will control the spin states at the transition metal center. The immediate goal of this project is the switching of spin states through external stimuli. A long-term goal is the modification of the reactivity at the transition metal center through a control of its spin state.