Soft-Template-Assisted On-Water Surface Synthesis of 2D Polymers (A03)

该项目将致力于利用软模板辅助的方法，通过动态共价键在水中合成单层/少层(&lt；10层)的具有大结晶区(μm2)的卟啉基2DPs。此外，还将阐明相应的结构表征和反应机理。重点是了解软模板在2DPS合成中的作用，并解决单体的可控堆积、缺陷修复、聚合度的提高等问题。

The project will focus on the on-water surface synthesis of single-/few-layer (< 10 layers) porphyrin-based 2DPs with large crystalline domains (μm2) via dynamic covalent bonds by soft-template-assisted method. Moreover, the corresponding structural characterization and reaction mechanism will be elucidated. Special focus will be given to the understanding of the role of soft-templates for the synthesis of 2DPs and to address the controllable stacking of the monomers, the defect repairing, the enhancement of the polymerization degree, etc.