Functionalization of hierarchical materials via active organic films (B10*)

项目B10旨在研究通过刺激敏感的有机层对分级纳米多孔金进行表面功能化的方法，以改进作为传感器和致动器材料的多功能软硬杂化材料的现有材料概念，并开发新的材料概念。这里使用了两种类型的有机涂层：聚吡咯的导电层和自组装的有机硫醇的单层。采用宏观实验方法和原子模拟方法，研究了电信号和化学刺激对杂化材料行为的定向控制。这些模拟的目的是在实验和原子水平上发生的过程之间建立一座桥梁。

Project B10 aims to investigate approaches for the surface functionalization of hierarchical nanoporous gold by stimulation-sensitive organic layers in order to improve existing material concepts for multifunctional hard-soft hybrids as sensor and actuator materials and to develop novel material concepts. Two types of organic coatings are used here: a conductive layer of polypyrrole and a monolayer of self-assembling organic thiols. The targeted control of the behavior of hybrid materials by electrical signals and chemical stimuli is investigated with experimental methods on the macroscale and simultaneously with atomic simulation methods. The simulations are intended to build a bridge between the experiments and the processes taking place at the atomic level.